Abstract

Climate change and global warming have been two massive concerns for the scientific community during the last few decades. Anthropogenic emissions of greenhouse gases (GHGs) have greatly amplified the level of greenhouse gases in the Earth's atmosphere which results in the gradual heating of the atmosphere. The precise measurement and reliable quantification of GHGs emission in the environment are of the utmost priority for the study of climate change. The detection of GHGs such as carbon dioxide, methane, nitrous oxide and ozone is the first and foremost step in finding the solution to manage and reduce the concentration of these gases in the Earth's atmosphere. The nanostructured metal oxide semiconductor (NMOS) based technologies for sensing GHGs emission have been found most reliable and accurate. Owing to their fascinating structural and morphological properties metal oxide semiconductors become an important class of materials for GHGs emission sensing technology. In this review article, the current concentration of GHGs in the Earth's environment, dominant sources of anthropogenic emissions of these gases and consequently their possible impacts on human life have been described briefly. Further, the different available technologies for GHG sensors along with their principle of operation have been largely discussed. The advantages and disadvantages of each sensor technology have also been highlighted. In particular, this article presents a comprehensive study on the development of various NMOS-based GHGs sensors and their performance analysis in order to establish a strong detection technology for the anthropogenic GHGs. In the last, the scope for improved sensitivity, selectivity and response time for these sensors, their future trends and outlook for researchers are suggested in the conclusion of this article.

Highlights

  • The whole world is craving for an environment on Earth plenteous of clean and fresh air

  • These studies lead to the good quality and efficient portable gas sensing devices, which have shown excellent sensitivities and selectivity; efficient fast response/recovery time; low operating temperature or even the ability to function independent of temperature which would lead to efficient power consumption; stability in the performance of the sensor in environment conditions; and minimum use of the chemically sensitive layer

  • This review article presents a comprehensive study of the role of nanostructured metal oxide semiconductor (NMOS)-based gas sensors in the detection of greenhouse gases (GHGs) and their potential to be used in commercial applications

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Summary

Introduction

The whole world is craving for an environment on Earth plenteous of clean and fresh air. The past four decades have seen incredible research in the development of MOS-based gas sensors which includes the production of innovative materials and associated fabrication technologies, and improved efficiency of sensors [13] These studies lead to the good quality and efficient portable gas sensing devices, which have shown excellent sensitivities and selectivity; efficient fast response/recovery time; low operating temperature or even the ability to function independent of temperature which would lead to efficient power consumption; stability in the performance of the sensor in environment conditions; and minimum use of the chemically sensitive layer. In the part of the introduction, we briefly discuss the current concentration of the major GHGs present in the troposphere of the Earth’s atmosphere and reported by several research agencies worldwide and their effects on human life with a view to emphasize the need for accurate detecting/ measuring NMOS-based tools for the GHGs

Concentration of greenhouse gases in the Earth’s environment
Concentration of nitrous oxide gas
Concentration of fluorocarbons
Severe impacts of greenhouse effect on human life
Ozone layer depletion
Change in rain patterns
Melting of glaciers and rising sea levels
Damage to coral reefs
Stronger storms
Shifting of wildlife species
Change in plant’s life cycle
Droughts
Gas sensors and their classification
Chemical gas sensors
Optical gas sensors
Electrochemical gas sensors
Catalytic gas sensor
Mass sensitive gas sensor
Magnetic gas sensors
Thermometric gas sensors
Photoacoustic spectroscopy
Chemiluminescence
2.10. Gas chromatography
2.11. Metal oxide semiconductor-based gas sensors
2.11.1. Gas sensing mechanism
2.11.2.1. Response
Metal oxide semiconductor-based carbon dioxide gas sensors
Metal oxide semiconductor-based methane gas sensors
Metal oxide semiconductor-based nitrous oxide gas sensors
Metal oxide semiconductor-based ozone gas sensors
Findings
Conclusion
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