Nanostructured Black Aluminum Prepared by Laser Direct Writing as a High-Performance Plasmonic Absorber for Photothermal/Electric Conversion.

Abstract

Utilizing the abundant and renewable solar energy to address the global energy shortage and water scarcity is promising. Great effort has been devoted to photothermal conversion for its typically full-spectrum utilization and high efficiency. Here, the coral-like micro/nanostructure was fabricated on an aluminum sheet by a facile laser direct writing technology. The nanocluster and microscale branches of corals endowed this black aluminum with broad-band plasmonic absorption and rapid heat transfer from the light absorption region to substrate. The black aluminum achieved ultrahigh solar absorbance of over 92.6% (>95.1% in the visible range) and excellent light heating ability (>90.6 °C under 1.0 sun). With good photothermal properties, this plasmonic absorber was used in a state-of-the-art eight-layer membrane distillation system, producing a water yield of up to 2.40 kg m-2 h-1 and a high solar conversion efficiency of 166.5% under 1-sun irradiation. Photothermal electricity was also achieved based on this system with a thermoelectric generator, with a water yield of 0.89 kg m-2 h-1 and a maximum electrical power output of 7.21 μW cm-2 under 1.0 sun. Considering the excellent performance of the plasmon-enhanced black aluminum, this work provides an alternative and feasible route toward high-efficient utilization of the solar energy.