Nanostructure characterisation of welded polyethylene using small angle X-ray scattering

Abstract

Polyethylene (PE), a common thermoplastic polymer, is gaining prominence in the construction and packaging industries due to its exceptional mechanical properties, chemical resistance, safety, and integrity. However, internal defects can occur during manufacturing and throughout its service life. Neglecting this problem results in the disposal of plastic and, consequently, the accumulation of plastic waste and environmental issues, which have caused much criticism. A common method to repair the thermoplastics is welding, which introduces seams and localized thermal residual stress fields resulting in areas where damage can nucleate, potentially leading to cracks and failure over time. These cracks often start at the nanoscale and propagate to larger length scales until failure occurs. The objective of this research paper is to develop welding processes, with improved integrity and lifespan for PE. Additionally, it aims to investigate and assess the impact of PE welding on parent materials at nano- and micron-scales, to understand limitations that are challenging to overcome in such welding processes. The study involves joining PE panels together under various pre-heating and post-cooling conditions, followed by evaluating the environmental stress cracking resistance of the welds and the durability of the repaired components. The crystallinity and morphology of the PE material in the weld area and its surrounding regions were analysed using Small Angle X-ray Scattering (SAXS), and the findings were compared with results obtained from optical microscopy and Differential Scanning Calorimetry. The study concludes that SAXS results offer exceptional information about the parent PE and weld material within the welding zone.