Nanosized Supramolecular Coordination Polymers Derived from Divalent Metal Ions, 4-Pyridylacetate and Auxiliary Ligands Containing Nitrogen and Phosphorus Donors

Abstract

A series of coordination polymers of Co(II), Ni(II), Cu(II) or Cd(II) comprising 4-pyridylacetate (pya) and certain auxiliary ligands including benzimidazole (Hbzim), 1,10-phenanthroline (phen), 2,2'-bipyridine (2,2'-bipy), 2-amino-4-methylthiazole (A-Mtz), quinazole (Quz), 2,5-dimethylpyrazine (dpmz), bis(diphenylphosphino)methane (dpm), 1,2-bis(diphenylphosphino)ethane (dpe) and 1,3-bis(diphenylphosphino) propane (dpp) were prepared and characterized by spectroscopic, magnetic and thermal techniques. In these coordination polymers 4-pyridylacetate coordinates to the metal ions in a monodentate fashion through the carboxylate oxygens and/or the pyridyl nitrogen. Octahedral structures around the metal ions were suggested for all the complexes. The kinetic analyses of the thermal decomposition of the complexes were studied using the Coats-Redfern equation. The kinetic and thermodynamic parameters of the thermal decomposition were also calculated and discussed. From the X-ray powder diffraction data, the crystal parameters as well as the particle sizes (15.7-18.7 nm) of the complexes could be evaluated. Some of the compounds exhibit catalytic activity. The biological activity of the compounds was screened as well. DOI: http://dx.doi.org/10.17807/orbital.v13i1.1551