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Abstract
In situ synchrotron X-ray diffuse scattering and inelastic neutron scattering measurements from a prototype ABO3 ferroelectric single-crystal are used to elucidate how electric fields along a nonpolar direction can enhance its piezoelectric properties. The central mechanism is found to be a nanoscale ordering of B atom displacements, which induces increased lattice instability and therefore a greater susceptibility to electric-field-induced mechanical deformation.
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