Nano-micron composite lithium-rich cathode materials prepared by oxalic acid one-step method

Abstract

Lithium-rich material (SOP) with special nano-micron composite structure is synthesized by simple one-step oxalic acid method. The SOP sample is made of micron particles (1–3 μm) and nano-particles (~ 100 nm). Compared with the co-precipitation prepared lithium-rich materials (COP), SOP has good rate performance and cycle stability. The specific discharge capacity of SOP sample reaches 104.2 mAh/g at 10 C, while that of COP sample is only 68.5 mAh/g. After 300 cycles, SOP still has a specific discharge capacity of 201 mAh/g and the capacity retention rate is 89.6%, while COP only has a specific discharge capacity of 135.8 mAh/g and the capacity retention rate is 58%. Structure allocation with nano-micron particles is conducive to electrochemical performance improvement. This study provides a new idea for the synthesis of lithium-rich material with better performance.