Nanomechanical characterization of the hydrogen effect on high strength steels

Abstract

The effect of hydrogen charging on nanohardness (HIT), elastic work (Welast), and plastic work (Wplastic) was investigated using nanoindentation. To accomplish this, two high-strength low-alloy steels (AISI 4130 M and AISI 4137 M) were tested using electrochemical nanoindentation with different loading rates (5 mN/min and 15 mN/min). Additionally, a continuous multicycle (CMC) indentation loading profile was proposed to assess the hydrogen embrittlement (HE) effect on AISI 4130 M steel. Under a current density of 0.5 mA/cm2 and 5 mN/min loading rate, AISI 4137 M steel exhibited a 30.6% reduction in Welast and a 9.8% increase in HIT value. In contrast, under the same conditions, Welast increased by 5.0% for AISI 4130 M steel. For the CMC indentation tests conducted on AISI 4130 M steel, both HIT and Welast values were affected, as evidenced by a reduction between 7% and 10% in HIT and between 4% and 22% in Welast. The lower deformation rates resulting from long-term CMC-type indentations enable hydrogen to follow the dislocation movement. In the experimental setup under study, the hydrogen-induced softening caused by the shielding of the elastic fields was observed as a reduction in nanohardness.