Nanoengineered pure Fe in a citrate matrix (Fe–CIT) with significant and tunable magnetic properties

Abstract

This work demonstrates the synthesis and characterization of Fe nanoparticles surrounded by a citrate (CIT) matrix prepared at various temperatures and concentrations of metal, capping agent and reducing agent at standard conditions. We study the effect of reactant ratio and reaction temperature on the magnetization of the produced nanoparticles and their crystal structure. We found that for optimal metal concentrations, magnetic saturation increases with increase in the concentration of capping and reducing agents but decreases as the temperature of the reaction increases. Synthesis conditions were tailored to reveal nucleation of particles with average sizes ranging from 24 to 105 nm and a spherical shape. The ultra-high saturation magnetization of 228 emu g-1obtained for samples prepared at a metal precursor concentration of 27.8 mol l-1was attributed to the formation of small magnetic domains. Energy band gap measurements revealed a band gap energy for the Fe nanoparticles in the CIT matrix which is associated with CIT concentration and/or possible formation of a few thin layers of iron oxide shell and does not have a significant effect on the magnetic properties of the samples. Herein, we demonstrate that the synthesis parameters are crucial for the nucleation of Fe-CIT nanoparticles tailoring their magnetizatic properties as well as their potential for different applications.