Abstract

Sensitive porous tungsten oxide nano-crystalline based NO 2 sensor was fabricated by thin film microfabrication technique. The sensitivity of this NO 2 sensor was at parts per billion (ppb) level. The nano-crystalline porous tungsten oxide film was prepared from WCl 6 by a sol–gel technique. The surface morphology and sensitivity to NO 2 of the tungsten oxide films calcined at various temperatures were investigated. The NO 2 adsorption behavior on the tungsten oxide surface was carried out by XPS measurement. Experimental results indicated that the tungsten oxide film calcined at 550 °C for 1 h showed the best performance as a sensing material to NO 2, and the optimal operational temperature of the sensor was 300 °C. The sensor showed high sensitivity to low NO 2 concentration in the range from 50 to 550 ppb with relatively fast response time (∼3 min) and recovery time (∼1 min), respectively.

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