Nanocrystalline celluloses-assisted preparation of hierarchical carbon monoliths for hexavalent chromium removal

Abstract

Hierarchical porous carbon monoliths with a 3D framework were synthesized through a facile sol–gel process using resorcinol-melamine–formaldehyde (RMF) as carbon precursors, and nanocrystalline celluloses (NCCs) as the structural inducing agent, followed by ambient pressure drying and carbonization. Polymerization of the RMF resin occurs around the nanorod-like NCCs dispersed homogeneously in water, which is quite beneficial for the formation of an interconnected network and supports the rigid macroporous structure. A hierarchical porous carbon monolith with modest micropores and well-developed macropores was prepared after CO2 activation at 950°C. The microporous structure was generated from the network of RMF polymer chains, while the macroporous structure was formed from the interconnection of polymer networks induced by NCCs. The obtained carbon monolith has a large specific surface area of 1808m2g−1 and shows a high adsorption capacity of 463mgg−1 for toxic Cr(VI) ions. Moreover, the activated carbon monolith exhibits a high selectivity for Cr(VI) in the coexistence of several other metal ions. These outstanding advantages of carbon monoliths, including their micro/macroporous structures, rich functional groups, low cost and easy synthesis, endow them with potential for use in a wide range of applications.