Abstract

—The spectrum of fractoluminescence (FL) upon fracture of the surface of oligoclase is obtained. The analysis of the spectrum has shown that fracture of crystals leads to the formation of electronically excited free radicals ≡Si−O• and Fe3• ions as well as electron traps. FL consisted of a set of the signals with the intensities varying by an order of magnitude. The duration of the signals was ~50 ns and the time interval between them varied from ~0.1 to 1 μs. Each signal contained four maxima associated with the destruction of barriers preventing the motion of dislocations along the sliding planes. These breakthroughs cause the formation of the smallest (“primary”) cracks. All other, larger cracks are formed by the coalescence of the “primary” cracks. The sizes of “primary” cracks range from ~10 to 20 nm and the time of their formation is 16 ns. The distribution of cracks by size (surface areas of crack walls) is power law with the exponent –1.9.

Highlights

  • Crack dynamics in rocks was studied from acoustic emissions (AE) (Zhurkov et al, 1981; Lockner et al, 1992; Sobolev and Ponomarev, 2003)

  • A few years ago, smaller cracks in rocks have come to be studied by a fractoluminescence method (Vettegren et al, 2020a; 2020b; 2021)

  • This method is based on the detection and analysis of fractoluminescence signals emitted from the fracture of mineral crystals

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Summary

Nanocracks upon Fracture of Oligoclase

Abstract—The spectrum of fractoluminescence (FL) upon fracture of the surface of oligoclase is obtained. The duration of the signals was ~50 ns and the time interval between them varied from ~0.1 to 1 μs. Each signal contained four maxima associated with the destruction of barriers preventing the motion of dislocations along the sliding planes. These breakthroughs cause the formation of the smallest (“primary”) cracks. The sizes of “primary” cracks range from ~10 to 20 nm and the time of their formation is 16 ns. The distribution of cracks by size (surface areas of crack walls) is power law with the exponent –1.9

INTRODUCTION
STUDY OBJECT AND METHODS
OLIGOCLASE FL SPECTRUM
MECHANISM OF NANOCRACK FORMATION UPON OLIGOCLASE FRACTURE
DYNAMICS OF FL SIGNALS
NANOCRACKS UPON FRACTURE OF OLIGOCLASE
What is the cause of this form of dependence
DISTRIBUTION OF FL SIGNALS BY INTENSITY
CONCLUSIONS
OPEN ACCESS
Full Text
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