Nanocage-based {In2Tm2}-organic framework for efficiently catalyzing the cycloaddition reaction of CO2 with epoxides and Knoevenagel condensation

Abstract

The combination of [In2Tm2(μ2-OH)2(CO2)10(H2O)2] clusters and H5BDCP ligand generated a highly robust nanoporous MOF with high catalytic performance in the cycloaddition reaction of epoxides with CO2 and Knoevenagel condensation.