Nanoarchitectonics of zirconium modified ZnTiO3 for photo and electro-catalysts in dye degradation and water splitting applications

Abstract

Perovskite oxides are attractive in the catalytic application owing to their stability, tuning characteristics, and easy synthesis process. Here, ZnTi1-xZrxO3 (x = 0.5) (abbreviated as ZZT0.5) is synthesized under the chemical precursor solution decomposition method and calcined at 700 °C for 3 h. The cubic phase nanosized material exhibits cubic shape morphology with the proper ratio of the existing elements as from observed structural and morphological characterizations. In the photocatalytic dye degradation under natural sunlight irradiation, the materials show >90% color degradation of congo red and murexide. The observed result in the presence of solar light irradiation highlights an elevated photocatalytic efficiency. The pseudo-first-order degradation process shows a high correlation coefficient with good stability of the material in the reusable study. This ZnTiO3-based perovskite material has not been used previously in electrocatalytic water splitting. During oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) conditions, the material deposited on NF substrate showed 335 mV and 165 mV overpotential at 10 mA cm−2 current density, respectively which is indicative of notable electrocatalytic water splitting activity of the perovskite material designed herein. The long-term chronoamperometry (CA) study confirms the material's stability during both HER and OER conditions with negligible loss in activity over a period of 12 h. The post-catalytic characterizations confirm the robust nature of the material possessing the same phase characteristics. As an earth-abundant, low-cost material, the material designed herein shows the significant activity of environmental sustainability in terms of water treatment as well as green hydrogen production via electrolysis.