Abstract

Due to its high sensitivity, low price and fast response speed, gas sensors based on metal oxide nanomate-rials have attracted many researchers to modify and explore the materials. First, pure indium oxide (In2O3) nanotubes (NTs)/porous NTs (PNTs) and Ho doped In2O3 NTs/PNTs are prepared by electrospinning and calcination. Then, based on the prepared nanomaterials, the 6-channel sensor array is obtained and used in the electronic nose sensing system for wine product identification. The system obtains the frequency signals of different liquor products by means of 6-channel sensor array, analyzes the extracted electronic signal characteristic information by means of ordinary least squares, and introduces the pattern recognition method of moving average and linear discriminant to identify liquor products. In the experiment, compared with pure In2O3 NTs sensor, pure In2O3 PNTs sensor has higher sensitivity to 100 ppm ethanol gas, and the sensitivity is further improved after mixing Ho. Among them, 6 mol% Ho + In2O3 PNTs have the highest sensitivity and the shortest response time; based on the electronic nose system composed of prepared nanomaterial sensor array, frequency signals of different Wu Liang Ye wines are collected. With the extension of acquisition time, the corresponding frequency first decreases and then becomes stable; the extracted liquor characteristic signal is projected into two-dimensional space and three-dimensional space. The results show that the pattern recognition system based on this method can extract the characteristic signals of liquor products and distinguish them.

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