Abstract
Cocondensation of FeCI2 and FeBr2 with CO/Ar leads either to species of the composition FeX2·n CO, whose vco stretching vibration is of higher frequency than that of free CO, or to the hitherto unknown complexes trans‐[Fe(CO)4X2], X = CI, Br. In the case of FeI2, only trans‐[Fe(CO)4I2] has been detected, and in the case of FeF2 exclusively FeF2·n CO adducts are formed, even with pure CO at 35 K. These findings are of significance for an understanding of sorption phenomena.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Angewandte Chemie International Edition in English
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
