Abstract

The purpose of this study is to synthesize transition metal doped mesoporous silica catalyst and to characterize its surface in an attempt to decomposition of <TEX>$N_2O$</TEX>. Transition metal used to surface modification were Ru, Pd, Cu and Fe concentration was adjusted to 0.05 M. The prepared mesoporous silica catalysts were characterized by X-ray diffraction, BET surface area, BJH pore size, Scanning Electron Microscopy and X-ray fluorescence. The results of XRD for mesoporous silica catalysts showed typical the hexagonal pore system. BET results showed the mesoporous silica catalysts to have a surface area of 537~973 <TEX>$m^2/g$</TEX> and pore size of 2~4 nm. The well-dispersed particle of mesoporous silica catalysts were observed by SEM, the presence and quantity of transition metal loading to mesoporous surface were detected by XRF. The <TEX>$N_2O$</TEX> decomposition efficiency on mesoporous silica catalysts were as follow: Ru>Pd>Cu>Fe. The results suggest that transition metal doped mesoporous silica is effective catalyst for decomposition of <TEX>$N_2O$</TEX>.

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