N-[(2-Chloro-8-methylquinolin-3-yl)methyl]-4-methoxyaniline

Raouf Boulcina,Thierry Roisnel,Sofiane Bouacida,Nassima Benhamoud,Abdelmadjid Debache

doi:10.1107/s1600536810041061

Abstract

In the title compound, C18H17ClN2O, the quinoline ring system is essentially planar; the r.m.s. deviation for the non-H atoms is 0.04 Å with a maximum deviation from the mean plane of 0.026 (4) Å for the C atom bonded to the –CH2– group. The methoxy-substituted benzene ring forms a dihedral angle of 70.22 (4)° with this ring system. The crystal structure can be described as zigzag layers in which the quinoline ring systems are parallel to (011) and molecules are connected via intermolecular N—H⋯N hydrogen bonds, forming chains along [100]. The crystal studied was an inversion twin with a 0.86 (5):0.14 (5) domain ratio.

Highlights

Structure ReportsCrystal data a Laboratoire des Produits Naturels d’Origine Végétale et de Synthèse Organique, PHYSYNOR, Université Mentouri–Constantine, 25000 Constantine, Algeria, bUnité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Faculté des Sciences Exactes, Département de Chimie, Université Mentouri–
Centre de difractométrie X, UMR 6226 CNRS Unité Sciences Chimiques de Rennes, Université de Rennes I, 263 Avenue du Général Leclerc, 35042 Rennes, France
Atoms is 0.04 Å with a maximum deviation from the mean plane of 0.026 (4) Å for the C atom bonded to the –CH2

Summary

Structure Reports

Crystal data a Laboratoire des Produits Naturels d’Origine Végétale et de Synthèse Organique, PHYSYNOR, Université Mentouri–Constantine, 25000 Constantine, Algeria, bUnité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Faculté des Sciences Exactes, Département de Chimie, Université Mentouri–. R factor = 0.027; wR factor = 0.070; data-to-parameter ratio = 16.5. C18H17ClN2O, the quinoline ring system is essentially planar; the r.m.s. deviation for the non-H atoms is 0.04 Å with a maximum deviation from the mean plane of 0.026 (4) Å for the C atom bonded to the –CH2–. The crystal structure can be described as zigzag layers in which the quinoline ring systems are parallel to (011) and molecules are connected via intermolecular N—H N hydrogen bonds, forming chains along [100].

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