Abstract

The title compound, C13H11N3O3, crystallized with two independent mol­ecules in the asymmetric unit. One of the mol­ecules is twisted while the other is almost planar, with dihedral angles of 28.02 (6) and 2.42 (9)°, respectively, between the benzene and pyridine rings. Intra­molecular O—H⋯O and O—H⋯N hydrogen bonds are present in both mol­ecules. The two independent mol­ecules are linked by pairs of O—H⋯O hydrogen bonds. The crystal structure is further stabilized by inter­molecular N—H⋯N hydrogen bonds and C—H⋯N and C—H⋯O inter­actions.

Highlights

  • The title compound, C13H11N3O3, crystallized with two independent molecules in the asymmetric unit

  • The two independent molecules are linked by pairs of O—H O hydrogen bonds

  • The crystal structure is further stabilized by intermolecular N—H N hydrogen bonds and

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Summary

Şenyüzb and Hümeyra Batıb*

Refinement a Department of Physics, Arts and Sciences Faculty, Ondokuz Mayıs University, 55139 Samsun, Turkey, and bDepartment of Chemistry, Arts and Sciences Faculty, Ondokuz Mayıs University, 55139 Samsun, Turkey. R factor = 0.038; wR factor = 0.084; data-to-parameter ratio = 11.8. The title compound, C13H11N3O3, crystallized with two independent molecules in the asymmetric unit. One of the molecules is twisted while the other is almost planar, with dihedral angles of 28.02 (6) and 2.42 (9) , respectively, between the benzene and pyridine rings. H O and O—H N hydrogen bonds are present in both molecules. The two independent molecules are linked by pairs of O—H O hydrogen bonds. The crystal structure is further stabilized by intermolecular N—H N hydrogen bonds and.

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