Abstract
AbstractA series of novel multifunctional carbenes of the type N‐phosphine imide‐substituted imidazolylidenes (PimIms) has been synthesized and characterized. Substituents including (+)‐10‐camphorsulfonyl and pyroglutamate groups were introduced on the N‐phosphinimidoyl moiety to diversify available structures of isolable carbenes. The impact that the rotation of the N‐phosphinimidoyl groups has on the spatial environment surrounding the carbene carbon atoms was evaluated theoretically. This analysis suggested that the shape as well as the volume of the reaction field around the carbene carbon atoms varies drastically during this rotation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
