N,N,N′,N′,N″‐Pentamethyl‐N″‐[(trifluorosilyl)methyl] phosphoric triamide. First example of the existence of intramolecular PO→Si coordination bond in the Si‐containing phosphoric triamides

Nataliya F Lazareva,Alexander I Albanov,Vadim A Pestunovich,Igor M Lazarev

doi:10.1002/aoc.1174

N,N,N′,N′,N″‐Pentamethyl‐N″‐[(trifluorosilyl)methyl] phosphoric triamide. First example of the existence of intramolecular PO→Si coordination bond in the Si‐containing phosphoric triamides

Nataliya F Lazareva, Alexander I Albanov + Show 2 more

https://doi.org/10.1002/aoc.1174

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Journal: Applied Organometallic Chemistry	Publication Date: Mar 6, 2007
Citations: 5

#Phosphoric Triamides #Phosphoric Triamide + Show 3 more

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Abstract

AbstractThe N,N,N′,N′,N″‐pentamethyl‐N″‐(trifluorosilylmethyl)phosphoric triamide OP(NMe2)2N(Me) CH2SiF3 with intramolecular PO→Si coordination was formed by the reaction of N,N,N′,N′,N″‐pentamethyl‐N″[(triethoxysilyl)methyl]phosphoric triamide with BF3·Et2O. Copyright © 2007 John Wiley & Sons, Ltd.

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