Abstract

The title compound, C32H21N4·C2H5OH, crystallized as an ethanol monosolvate. In the mol­ecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The tri­phenyl­amine group, introduced as an electron donor, shows a propeller-type structure, and the dihedral angles between the benzene rings are 68.71 11), 63.92 (16) and 70.81 (15)°. In the crystal, the phenanthroline mol­ecules are linked via the solvent mol­ecule by N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, leading to the formation of zigzag chains propagating along [010]. These chains are linked via C—H⋯N hydrogen bonds, forming undulating two-dimensional networks extending in the a- and b-axis directions.

Highlights

  • The title compound, C32H21N4C2H5OH, crystallized as an ethanol monosolvate

  • The phenanthroline molecules are linked via the solvent molecule by N—H O, O—H N and C—H O hydrogen bonds, leading to the formation of zigzag chains propagating along

  • These chains are linked via C—H N hydrogen bonds, forming undulating two-dimensional networks extending in the a- and b-axis directions

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Summary

Crystal data

In the molecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13). The triphenylamine group, introduced as an electron donor, shows a propeller-type structure, and the dihedral angles between the benzene rings are 68.71 11), 63.92 (16) and 70.81 (15). The phenanthroline molecules are linked via the solvent molecule by N—H O, O—H N and C—H O hydrogen bonds, leading to the formation of zigzag chains propagating along [010]. These chains are linked via C—H N hydrogen bonds, forming undulating two-dimensional networks extending in the a- and b-axis directions

Bruker APEXII CCD diffractometer
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This work was supported by a grant from the National
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