Year-end Sale % OFF 
Abstract
In the title compound, C27H25NP2, the diphenylphosphino groups are staggered relative to the PNP backbone. The dihedral angles between the phenyl rings bonded to each P atom are 51.74 (5) and 68.23 (4)°. The coordination around the N atom deviates from trigonal-pyrimidal geometry towards an almost planar arrangement between the N atom and the adjacent P and C atoms; the distance between the N atom and the plane formed by the adjacent C/P/P atoms is 0.098 (2) Å.
Highlights
C27H25NP2, the diphenylphosphino groups are staggered relative to the PNP backbone
The coordination around the N atom deviates from trigonal-pyrimidal geometry towards an almost planar arrangement between the N atom and the adjacent P and C atoms; the distance between the N atom and the plane formed by the adjacent C/P/P atoms is 0.098 (2) A
Related literature For similar non-coordinated diphosphineamine ligands with distorted trigonal-pyramidal geometries see: Fei et al (2003); Keat et al (1981); Cotton et al (1996); Cloete et al (2008, 2009, 2010)
Summary
Related literature For similar non-coordinated diphosphineamine ligands with distorted trigonal-pyramidal geometries see: Fei et al (2003); Keat et al (1981); Cotton et al (1996); Cloete et al (2008, 2009, 2010)
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
