Abstract
The title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a four-membered titanacycle obtained from the reaction of Cp2Ti(η2-Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis[bis(trifluoroethoxy)phosphanyl]methylamine, tfepma}. The TiII atom is coordinated by two cyclopentadienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetrahedral geometry. The molecule is located on a mirror plane.
Highlights
The title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a fourmembered titanacycle obtained from the reaction of Cp2Ti(2Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis[bis(trifluoroethoxy)phosphanyl]methylamine, tfepma}
The molecule is located on a mirror plane
The molecule is located on a mirror plane which passes through H5A, C5, N1, Ti1, C7, H7, C11 and H11
Summary
{N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine-j2P,P0 }bis(g5cyclopentadienyl)titanium(II) Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse R factor = 0.031; wR factor = 0.079; data-to-parameter ratio = 17.9. The title compound, [Ti(C5H5)2(C9H11F12NO4P2)], is a fourmembered titanacycle obtained from the reaction of Cp2Ti(2Me3SiC2SiMe3) and CH3N[P(OCH2CF3)2]2 {N,N-bis[bis(trifluoroethoxy)phosphanyl]methylamine, tfepma}. The TiII atom is coordinated by two cyclopentadienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetrahedral geometry. The molecule is located on a mirror plane.
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