Abstract
The asymmetric unit of the title compound, [Cd(C7H4NO3S)2(C8H22N4)]·0.25H2O, consists of two [Cd(sac)2(paen)] molecules [sac is saccharinate (C7H4NO3S) and paen is N,N′-bis(3-propylamine)ethylenediamine (C8H22N4)], and a partial- occupancy water molecule. Each CdII ion is octahedrally coordinated. The equatorial plane of the octahedron is formed by N atoms of the paen ligands, and the axial positions are occupied by the N atoms of the sac ligands. In one of the molecules, the sulfonyl group of a sac ligand is disordered over two different orientations, with site-occupancy factors of 0.83 and 0.17. N—H⋯O hydrogen bonding is observed between the independent molecules. Neighbouring [Cd(sac)2(paen)] units are linked by N—H⋯O hydrogen bonds into chains running parallel to the a axis.
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