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Abstract
The title compound, [Ni(C20H14N2S2)], was formed from a Schiff base reaction of 2-tert-butylthiobenzaldehyde with 1,2-phenylenediamine, followed by reaction with Ni(BF4)2.6H2O. The square-planar NiN2S2 complex has Ni—N distances of 1.8992 (17) and 1.9014 (15) Å, and Ni—S distances of 2.1519 (6) and 2.1587 (6) Å. Molecules pack in layers with a tilt angle of 46.09 (1)°; the (0 0 1) packing plane is arranged so that the molecules in superimposed layers stack approximately perpendicular to each other.
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