Abstract
The molecular structure of the title compound, C22H28N6S2, is the first crystallographically determined guanidine ligand containing sulfur. It shows two guanidyl groups bridged by a diphenyldisulfanyl linker with localized C=N bonds. The C—S—S—C group has a folded nonplanar conformation like that found in H2O2 or H2S2, with a torsion angle of 84.65 (10)°. The S—S bond length is 2.0435 (7) Å. Molecules are linked by C—H⋯N hydrogen bonds. The crystal studied was an inversion twin with approximately 2:1 components.
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