Abstract

The title mol­ecule, C22H16N2O4, is a 2,2′-disubstituted biphenyl whose phenyl­ene rings are rotated by 66.5 (1)° so as to avoid repulsion by the substituents. Only one of the two amide –NH– fragments engages in hydrogen bonding, and this inter­acts with the amido –C(=O)– acceptor of an inversion-related mol­ecule to generate a hydrogen-bonded dimer.

Highlights

  • The title molecule, C22H16N2O4, is a 2,20 -disubstituted biphenyl whose phenylene rings are rotated by 66.5 (1) so as to avoid repulsion by the substituents

  • One of the two amide –NH– fragments engages in hydrogen bonding, and this interacts with the amido –C( O)– acceptor of an inversionrelated molecule to generate a hydrogen-bonded dimer

  • H atoms treated by a mixture of independent and constrained refinement max = 0.33 e Å3

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Summary

Bruker SMART APEX diffractometer

One of the two amide –NH– fragments engages in hydrogen bonding, and this interacts with the amido –C( O)– acceptor of an inversionrelated molecule to generate a hydrogen-bonded dimer

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