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Abstract
In the title compound, [Cu(C34H24N4O2S2)] or [Cu(bqdapte)], where H2bqdapte is 1,2-{bis[2-(quinoline-2-carboxamido)phenyl]sulfanyl}ethane, the CuII ion is coordinated to the dianionic hexadentate bqdapte2− ligand by two amide and two quinoline N atoms and two thioether S atoms. In the observed conformation of the hexadentate ligand, the quinoline rings attain positions related by a twofold axis. The Cu atom displays a Jahn–Teller-distorted octahedral CuN4S2 geometry axially compressed along the two trans-configured Cu—Namidate bonds.
Highlights
Structure Reports{N,N0 -[2,20 -(Ethane-1,2-diyldisulfanediyl)di-o-phenylene]bis(quinoline-2carboxamidato)}copper(II) Soraia Meghdadi,a* Valiollah Mirkhania and Peter C. Fordb a Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran, and Department of Chemistry and Biochemistry, University of California, Santa Barbara, California, 93106, USA
In the title compound, [Cu(C34H24N4O2S2)] or [Cu(bqdapte)], where H2bqdapte is 1,2-{bis[2-(quinoline-2-carboxamido)phenyl]sulfanyl}ethane, the CuII ion is coordinated to the dianionic hexadentate bqdapte2 ligand by two amide and two quinoline N atoms and two thioether S atoms
In the observed conformation of the hexadentate ligand, the quinoline rings attain positions related by a twofold axis
Summary
{N,N0 -[2,20 -(Ethane-1,2-diyldisulfanediyl)di-o-phenylene]bis(quinoline-2carboxamidato)}copper(II) Soraia Meghdadi,a* Valiollah Mirkhania and Peter C. Fordb a Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran, and Department of Chemistry and Biochemistry, University of California, Santa Barbara, California, 93106, USA
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