Abstract
The 1H- and 13C-n.m.r. spectra of 2-acetamido-2-deoxy derivatives of methyl d-gluco- and d-galacto-pyranoside were measured in the presence of lanthanide ions in deuterium oxide. The signals of the N-acetyl protons, H-2, the carbonyl and methyl carbon atoms in the N-acetyl groups, and C-2 were more markedly shifted than others by the addition of praseodymium ion. The 13C-spin-lattice relaxation-times were also measured in the presence of gadolinium ion, and the distances between it and several carbon atoms were estimated. Based on all of the data, it is suggested that lanthanide ions may preferentially form a complex with the acetamido group, probably binding to the nitrogen atom in the amino sugars.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
