Abstract
AbstractAlkylbenzenes were aerobically oxidized to their oxygenated products via a novel catalytic system using N‐hydroxy‐1,6‐methano[10]annulene‐3,4‐dicarboximide (2) and cobalt(II) acetate under mild conditions. A radical mechanism has been proposed to account for the aerobic oxidation of these hydrocarbons. The 2/Co(OAc)2 catalytic system was optimized and the reaction scope was explored.
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