Abstract
1. N-(2-Hydroxy-3-aryloxypropyl)vinyloxyanilines have been obtained for the first time by reaction of vinyloxyanilines with glycidyl esters of phenols. 2. A linear relationship has been established linking the size of the pK a with the Hammett constants of substituents in an aromatic series of anilines (ρ=3.26). 3. In acetonitrile the basicity of N-(2-hydroxy-3-aryloxypropyl)vinyloxyanilines was increased as a result of additional stabilization of the conjugate acids of these bases by an intramolecular hydrogen bond.
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