Abstract

Oxyselenation reactions, which involve an electrophilic attack of organoselenium group on olefin and acetylene followed by a nucleophilic attack of oxygen atom of alcohol, carboxylic acid, water etc, are reviewed, especially focusing on the recent application to organic synthesis. The term of solvoselenation is introduced for the first time as a more general name for the oxyselenation type reaction in various solvents such as ROH, RCO2 H, RCN etc.

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