Abstract
This account outlines our studies on organic synthesis inspired by the relevance to carbohydrates in various ways. The contents include, (1) my personal encounter with carbohydrate synthesis, (2) cationic hafnocene species in glycoside synthesis, (3) aryl C-glycoside antibiotics, (4) O→ C-glycoside rearrangement, (5) [2+2+2] approach to phenylnaphthalene motif in polyaromatic natural products, (6) regioselective O-glycosylation of pseudo-C2 symmetric phenanthrenediols in the benanomicin-pradimicin antibiotics and TAN-1085, and (7) oligo (polyphenol) synthesis based on the analogy to carbohydrate chemistry.
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