Abstract
Complex fluid showed quite different characteristics from general solution. There are more rich and changeful properties and phase behavior in the complex fluid. The complex self-assemble structures in the complex fluid may result in special phase behavior. Understanding the phase equilibrium in the complex fluid is important to solve the problems in the production. The self-assemble structures, the special interaction, and the novel phase behavior in the complex fluid are reviewed from the perspective of chemical thermodynamics. For the liposome solution and salt lake brine solution, self-assemble structures, the special interaction, and phase equilibrium are introduced, respectively. And the effects of the self-assemble structure on phase behavior are discussed.
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