Abstract
This review describes the recent studies on organic photoreactions via charge-transfer complexes of small-ring compounds with various electron-acceptors, such as valence isomerizations, rearrangements, cycloadditions and oxygenations. In especial, mechanisms of oxygenations of three-membered compounds through the charge-transfer complexes with TCNE were discussed in detail, comparing with those reported for photoelectron transfer induced oxygenations.
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