Abstract

The viscosity of aqueous lithium chloride (LiCl) solution was measured at 0.1-375MPa, at 278.2-318.2K, and 0.5-4.0molkg-1. The Jones-Dole B coefficients for LiCl in water were obtained from the concentration dependence of the viscosity, and were divided into each ionic contribution. In the studied ranges of pressure and temperature, the B for Li+ ion decreases monotonically with increasing pressure. However, the B for Cl- ion increases with pressure up to 100-200MPa. Pressure dependence of the B for alkali metal ions (Li+, Na+, K+ and Cs+) were discussed supposing that the B consists of three terms, that is, Einstein effect (BE), dielectric friction effect for solvent (BD), and structural effect of solvent (BS).

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