Abstract
The title molecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-trimethylsilyfluorenyl lithium and 2-methoxybenzonitrile. The fluorene ring system is substantially planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7)° with the 2-methoxybenzylamine ring plane. In the crystal, molecules are linked by N—H⋯π and C—H⋯π interactions, which leads to the formation of two-dimensional network lying parallel to the bc plane.
Highlights
The title molecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-trimethylsilyfluorenyl lithium and 2-methoxybenzonitrile
H interactions, which leads to the formation of twodimensional network lying parallel to the bc plane
The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry
Summary
The title molecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-trimethylsilyfluorenyl lithium and 2-methoxybenzonitrile. The fluorene ring system is substantially planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7) with the 2-methoxybenzylamine ring plane. H interactions, which leads to the formation of twodimensional network lying parallel to the bc plane
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