Abstract

The title mol­ecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-tri­methyl­silyfluorenyl lithium and 2-meth­oxy­benzo­nitrile. The fluorene ring system is substanti­ally planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7)° with the 2-meth­oxy­benzyl­amine ring plane. In the crystal, mol­ecules are linked by N—H⋯π and C—H⋯π inter­actions, which leads to the formation of two-dimensional network lying parallel to the bc plane.

Highlights

  • The title molecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-trimethylsilyfluorenyl lithium and 2-methoxybenzonitrile

  • H interactions, which leads to the formation of twodimensional network lying parallel to the bc plane

  • The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry

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Summary

Data collection

The title molecule, C24H25NOSi, is a hydrolysis product of the reaction between 9-trimethylsilyfluorenyl lithium and 2-methoxybenzonitrile. The fluorene ring system is substantially planar, with an r.m.s. deviation of 0.0288 Å from the best-fit plane through its 13 C atoms. This plane forms a dihedral angle of 58.07 (7) with the 2-methoxybenzylamine ring plane. H interactions, which leads to the formation of twodimensional network lying parallel to the bc plane

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