MXene-based designer nanomaterials and their exploitation to mitigate hazardous pollutants from environmental matrices

Abstract

MXenes are a rapidly expanding and large family of two-dimensional (2D) materials that have recently garnered incredible research interests for diverse applications domains in various industrial sectors. Owing to unique inherent structural and physicochemical characteristics, such as high surface area, biological compatibility, robust electrochemistry, and high hydrophilicity, MXenes are appraised as a prospective avenue for environmental-clean-up technologies to detect and mitigate an array of recalcitrant hazardous contaminants from environmental matrices. MXene-based nanoarchitectures are thought to mitigate inorganic pollutants via interfacial chemical transformation and sorption, while three different mechanisms, including i) surface complexation and sorption (ii) catalytic activation and removal and (iii) radical's generation-based photocatalytic degradation, are involved in the removal of organic contaminants. Considering the application performance of MXenes on the incessant rise to expansion, in this review, we discuss the wide-spectrum applicability of diverse MXenes-based hybrid nanocomposites in environmental remediation. A brief description related to environmental pollutants, structural properties, chemical abilities, and synthesis route of MXenes is delineated at the start. Afterwards, the adsorption and degradative robustness of MXene-based designer nanomaterials for various contaminants including organic dyes, toxic heavy metals, pesticide residues, phenolics, antibiotics, radionuclides, and many others are thoroughly vetted to prove their potentiality in the arena of wastewater purification and remediation. Lastly, challenges and trends in assessing the wide-range applicability and scalability of MXenes are outlined. Seeing encouraging outcomes in plenty of reports, it can be concluded that MXenes-based nanostructures could be considered the next-generation candidates for water sustainability.