Mussel-Inspired Catechol-Grafted Quaternized Chitosan Flocculant for Efficiently Treating Suspended Particles and Refractory Soluble Organic Pollutants

Abstract

It remains challenging yet of great importance to develop a qualified biopolymer-derived flocculant in treating complex high-salinity wastewaters polluted by suspended solids and refractory soluble organic substances such as organic dyes. The key to this success is to endow the developed flocculants with versatile intermolecular and interfacial interactions in high salinity to trigger effective flocculation. Herein, inspired by mussel’s powerful wet adhesion in a salted marine environment to diverse interfaces, we develop a mussel-inspired chitosan-based flocculant (CQ-CS) by simultaneously grafting catechol and cationic trimethylammonium groups to chitosan backbones. Compared with its cationic compartment, the optimal dosage of CQ-CS is decreased greatly after introducing catechol groups. Moreover, CQ-CS works in a wide pH range from 2 to 7 and can achieve more than 95% removal efficiency of soluble organic dyes and suspended particles such as anionic dyes and kaolin clay at the optimal dosages. More importantly, the flocculation performance of CQ-CS exhibits excellent tolerance to the salinity. As NaCl concentration increases from 0 to 2000 mg/L, CQ-CS maintained similar removal efficiencies for organic dyes, while the removal efficiency of quaternized chitosan (Q-CS) for organic dyes decreased by approximately 8% at this salinity. Finally, CQ-CS exhibits excellent flocculation performance to industrial dyeing wastewaters.