Abstract

The temperature dependence of muon interactions has been studied in ferroelectric KDP ( H2KPO4) and DKDP ( D2KPO4) using conventional μSR and muon spin resonance spectroscopy. In longitudinal field measurements, a fast relaxing component and a slow relaxing component were observed. The slow relaxing component is attributed to diamagnetic muons. The muon spin resonance measurements indicate that the fast relaxing component results from some muonium like species: either normal or anomalous. In zero field and weak longitudinal field μSR (0–100 G), a remarkable peak in the fast relaxing component is observed around 220 K in both KDP and DKDP. An additional feature is also seen around 300 K. The amplitude of the resonance measurement has a broad minimum around 200 K which corresponds to the maximum in the relaxation rate in longitudinal field (100 G). The temperature dependence of the muonium relaxation rate in KDP is almost identical to that of DKDP. The diamagnetic fraction also shows almost no difference in relaxation rate or asymmetry for DKDP and KDP.

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