Municipal woody biomass waste ash-based cold-bonded artificial lightweight aggregate produced by one-part alkali-activation method

Abstract

The rapid industrialization process has resulted in the overconsumption of natural aggregates, leading to significant environmental concerns. Additionally, the disposal of municipal woody biomass ash (MWBA) has caused the depletion of land and further environmental pollution. Hence, production of artificial aggregate using MWBA is of great interest, as it reduces the consumption of natural aggregates and landfill area while recycling the MWBA. The main objective of this study is to determine the optimal mix design that can produce artificial aggregates with satisfactory strength and lightweight properties while maximizing the utilization of MWBA. Following that, the effects of different alkaline contents (9%, 12%, 15%) and ground granulated blast-furnace slag (GGBS) contents (0%, 10%, 20%, 30%) on the physical properties of the MWBA-based AAAs were investigated. Additionally, the pore distribution, phase and elemental compositions of the aggregates were examined to ascertain the mechanism of alkali-activation and strength development of the MWBA-based AAAs. The main result showed that at 15% Na2SiO3·5H2O content, increasing the GGBS content from 0% to 30% resulted in an increase in the loose bulk density and crushing strength of MWBA-based AAAs from 817 kg/m3 to 950 kg/m3 and from 0.84 MPa to 2.25 MPa, respectively, while decreasing the water absorption from 24.0% to 12.5%. This is due to the denser matrix observed, attributed to the GGBS addition, which enhances the effect of alkali-activation. Additionally, a new amorphous phase, namely C-A-S-H, was identified. The Si/Al ratio decreased with the GGBS content, resulting in more C-A-S-H gel formation and a denser microstructure with better performance for the AAAs. The novelty of this study is to demonstrate the feasibility of using MWBA in producing AAAs through a cold-bonded one-part alkali activation method. This method presents an alternative to natural aggregates that can be utilized in concrete.