Multiscale calculation results of the flow behavior in micro/nano porous filtration membrane with the adsorbed layer-fluid interfacial slippage

Abstract

The paper presents the multiscale calculation results for the multiscale flow in micro/nano porous filtration membranes where the adsorbed layer effect is involved, by considering the adsorbed layer-fluid interfacial slippage. The analysis consists of the molecular scale analysis for the adsorbed layer flow and the continuum analysis for the intermediate fluid flow. The calculation results are respectively compared with the classical flow theory calculations and those based on the solid layer assumption. The adsorbed layer flow rate is also compared with the flow rate of the intermediate continuum fluid. It is shown that for a strong fluid-pore wall interaction or for a large adsorbed layer-fluid interfacial slippage the adsorbed layer can be treated as a solid layer; otherwise it should be treated as a flowing layer. The large interfacial slippage results in the flow rate through the pore far greater than the classical Hagen-Poiseuille equation calculation; it largely propels the flow of the intermediate continuum fluid and makes the adsorbed layer flow negligible particularly for the medium and strong fluid-pore wall interactions. The increasing fluid-pore wall interaction strength significantly reduces the flow rate through the pore.