Abstract

A formalism is presented that enables the calculation of atomic charge and current densities in Russel-Saunders states of free atoms and ions in terms of scalar and vector spherical harmonics. The electric and magnetic fields generated by the multipole components of charge and current distributions are easily calculated. They are found to have the same multipolarity as their generating sources and Maxwell's equations are satisfied component by component. Calculations of these fields for hydrogenlike atoms and specific transition-metal and rare-earth ions are presented using realistic analytic radial wave functions. (C) 2008 Elsevier B.V. All rights reserved.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.