Abstract

Calculations of binding-energy curves and charge distributions have been carried out for low-lying states of ${\mathrm{Si}}_{2}$ and ${\mathrm{Ge}}_{2}$ using the local-density-functional formalism. Calculated spectroscopic constants are in good agreement with experiment for the states of ${\mathrm{Si}}_{2}$ which have been identified, so that predictions for other states should be reliable. The binding-energy curves of the two dimers are remarkably similar, as are the $s\ensuremath{-}p$ valence orbitals of silicon and germanium atoms. Charge-density differences are similar to those calculated previously for ${\mathrm{C}}_{2}$ and orbital densities show pronounced differences from results of a recent pseudopotential calculation, even in regions far from the cores.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.