Multiple regression analyses of kinetics of aquation reactions of some chromium (III) - alkyl amine complexes in mixed solvent media - A study of solvation mechanics

Abstract

Molecular dynamics of the aquation reactions of the complexes [Cr(en)2Cl2]Cl,[Cr(tn)2Cl2]Cl,[Cr(tetren)Cl]Cl2, [Cr(pn)2Cl2]Cl, [Cr(trien)Cl2]Cl and [Cr(dien)Cl3] have been extensively studied in mixed solvent media. Kinetics and thermodynamic parameters have been evaluated and the results are interpreted carefully in the light of statistical and regression models. Key words: Cr (III) complexes, molecular dynamics, aquation reaction, kinetic parameters, thermodynamic parameter, statistical model, regression model.