Abstract

Three new indium oxalates, formulated as H3dpta·In(C2O4)(H2O)3·2SO4 (1), In(qd)(C2O4)1.5·1.5H2O (2), and H2bpp·In2(C2O4)4 (3) in which dpta=dipropylenetriamine, qd=quinoxaline-2,3(1H,4H)-dione, and bpp=1,3-bis(4-piperidyl)propane, were prepared in the presence of different amines. These compounds have cationic, neutral, and anionic frameworks, respectively. Topological analyses reveal that compound 2 has an hcb net, while compound 3 has a dia net. The photoluminescent property of compound 2 was also investigated.

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