Multiple adulterants detection in turmeric powder using Vis-SWNIR hyperspectral imaging followed by multivariate curve resolution and classification techniques

Abstract

In the present contribution, visible and short wavelengths of near infrared hyperspectral imaging (Vis-SWNIR-HSI) combined with different chemometric techniques is proposed as a novel technique for turmeric authentication and multiple adulterants (corn flour, rice flour, starch, wheat flour, and zedoary) detection. In this regard, twenty-three samples of turmeric were collected as whole rhizomes or powdered from seven countries and then their VIS-SWNIR hyperspectral images were obtained in 400–1000 nm using SPECIM IQ HSI device. Two multivariate resolution techniques of multivariate curve resolution-alternating least squares (MCR-ALS) and mean-field independent component analysis (MF-ICA) were used to extract pure spatial and spectral profiles of the components, and their results were compared by projecting their solutions in the area of feasible solutions (AFSs). Then, the distribution maps of turmeric component obtained using MCR-ALS and MF-ICA were used for authentication. Principal component analysis (PCA) was used to find the pattern of authentic samples using their distribution maps. Additionally, data-driven soft independent modeling of class analogy (DD-SIMCA) was employed to find boundary between authentic and adulterated turmeric samples. On this matter, good class modelling results with sensitivity of 95 % and specificity of 100 % were obtained. Finally, partial least squares-discriminant analysis (PLS-DA) was utilized for discrimination of the of adulternats and their in binary and multi-class classification modes. On this matter, PLS-DA accuracies were acceptable for binary and mixed samples which confirmed the validity of the proposed method.