Abstract
The kinetics of ethylene polymerization catalyzed by Cp 2ZrCl 2–different aluminoxanes was studied. More than one type of active site was presented in the polymerization reaction based on an analysis of the GPC curves. A multiple active sites kinetic model (MSmodel) was proposed. Good agreements in polymerization rate and variation of polydispersity were achieved for fitting the kinetic profiles with the MSmodel.
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