Abstract

Ionisation/dissociation multiphotonique UV/visible de divers complexes: Fe 3 (CO) 12 , Ru 3 (CO) 12 , Os 3 (CO) 12 , Fe 2 Ru(CO) 12 , Fe 2 (CO) 6 S 2 et [(π-C 5 H 5 ) Cr(CO) 3 ] 2 . Formation d'ions moleculaires contenant un metal insature et d'ions metalliques atomiques. La photodissociation de complexes carbonyles metalliques stables fournit des echantillons en phase gazeuse de dimeres et trimeres homo- et heteronucleaires metalliques, de sulfures metalliques et d'atomes metalliques monocoordines

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