Multi-pathway on peroxymonosulfate activation by single cobalt atoms incorporated on CuO with enriched oxygen vacancies for high-efficient oxidation of tetracycline

Abstract

The development of single atom catalysts (SACs) with superior catalytic performance is a long-term goal for peroxymonosulfate (PMS) activation in advanced oxidation processes (AOPs). A novel SACs that single Co atoms anchored on CuO with enriched oxygen vacancies (Ov) is synthesized successfully by choosing a metal oxide as the carrier creatively. 100% of tetracycline (TC) can be removed by Co–CuO (Ov)/PMS system within 3 min. The corresponding reaction rate constant is 3.1068 min−1, which is much higher than that of CuO (Ov), ZIF-CoN4-C, Co–CuO (without Ov) and CoNP–CuO (Ov), respectively. Co(II) is the primary source of radical pathway (·OH and SO4·-), and its regeneration is promoted by Cu(Ⅰ). The enriched Ov is the major contribution to the nonradical pathway, which promotes the singlet oxygen (1O2) generation together with accelerates the electron transfer from TC to catalyst-PMS*. Besides, the Co–CuO (Ov) exhibits an excellent stability and anti-interference capability. This study highlights a novel strategy to promote PMS activation by incorporating the single metal atoms on a metal oxide carrier with defects to accelerate the redox of dominate metal and stabilize the metal atoms simultaneously, which may inform the design for the next generation of SACs in AOPs.